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That is what I meant by my comment in a previous posting that an
individual molecule does not know that it is moving from a wide pipe
into a narrower one. It only knows that the symmetry of its
collisions with the molecules around it is changing - it only
experiences the results of the laws of physics by banging into other
molecules in a purely local way.
I once wrote a simulation for this in FORTRAN. I started with a large
number of molecules in a box all with the same speed but traveling in
random directions in 3D. I then let them collide with each other
randomly and soon a Boltzmann distribution of speeds developed. Once
this part of the simulation was secure, I put the molecules in a pipe
with a restriction followed by a widening of the pipe. The molecules
were all given the same initial KE but with a slightly higher value
to the right for the component parallel to the pipe. I had the
molecules leaving one end of the pipe reappear back on the other end.
After a long run to establish an equilibrium flow, the molecules
moved faster through the constriction as expected. What disappointed
me was that I didn't learn anything I didn't already know about the
microscopic details of the process in the simulation versus a real
flow, The mechanism (on a molecular level) for the increased speed
and reduced pressure was not revealed r egardless of how I reduced
and presented the data about individual molecules.
It was the old
thing that the better a simulation gets the less sense it makes to
run it versus looking at the real process.