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Not sure how applicable this is "at the molecular level", but a heuristic (at
least in the limit of incompressible fluids) explanation is nice, and doesn't
rely on the mathematics, or at least on the notion of streamlines and the like.
Consider a pipe of cross-sectional area A1, which connects to a section of
smaller cross-sectional area A2. Continuity (which students can understand at a
gut-level, at least for incompressibles) says that the speed in the vicinity of
A2 must be higher than that near A1. For this to have happened, the linear
momentum of a given fluid parcel is higher at A2 than at A1, and so the pressure
at A1 has to have been higher than at A2.