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/snip/ The thermodynamics of electrolysis is straightforward. It is spelled out here: http://hyperphysics.phy-astr.gsu.edu/hbase/thermo/electrol.html
/snip/ Tangential remark: The hyperphysics site is quite good overall. It has wide coverage of physics topics. It is reasonably clear. It is incomparably more trustworthy than wikipedia.