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melting point of 32F, and so the liquid goes on getting denser until it
reaches a maximum density at 39F. Above this temperature, enough hydrogen
bonds have been broken that the liquid starts to behave normally (at least
more normally), becoming less dense with increasing temperature because the
thermal jiggling of the molecules tends to keep their neighbors at an
increasing distance."
Much modeling work is done on this topic at Boston University - by Gene
Stanley.
http://buphy.bu.edu/