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Picking up on something Brian Jones said at the summer AAPT meeting,
I'll say that experience comes first. He described how students,
allowed to play with florescent sheets and various colored LED's gain
understanding from that experience. When asked specific question
about light and energy later they have a sense that blue light has
more "something" than red light.
I say that (a) sometimes experience comes first, and (b) sometimes
it doesn't. Anecdotes of type "a" don't disprove "b".