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Maybe I missed the point, but it really doesn't matter if the air is exposed to the sun or not. Air is basically transparent to sunlight so its temperature is really set by its interaction with the ground (conduction - convection). The temperature in the shade is usually a pretty good indicator of air temperature. In fact, reporting stations have thermometers placed in louvered boxes to prevent direct sunlight from striking the thermometer while providing a relatively free flow of air. The sunlight striking your body, of course, makes it feel hotter.One could say I suppose, that the Sun offers the prospect of both convective and radiative heating. A person in sunlight is subject to both; a person in the shade is subject to convection. The former leads to a hotter outcome.
Bob at PC