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It seems to me that if you are looking for a qualitative
understanding of why excess charge (up to some limit)
does not fly off a charged metal surface, then the
explanation is relatively simple and can be understood
in purely classical terms. ....
... The electrons in the metal near that charge will be
repelled leaving a positive region in the metal which
serves to attract that electron and keep it from drifting
off into space. ... This happens because the Coulomb force
falls off as the square of the distance, so the positive
region near charge on the surface has a much greater
influence than the distributed charge further away.
Of course as I add more and more electrons, the coulomb
repulsion gets bigger and bigger, and eventually other
things happen.