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There are other problems, including abuse of the terms
"anode" and "cathode".
http://www.av8n.com/physics/anode-cathode.htm
From the keen-grasp-of-the-obvious department: If youwant to know which is positive, use a voltmeter.
If there is some heretofore-unmentioned constraint that
prevents you from using a voltmeter, you need to ask a
different question, being careful to say what the
constraints are.