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This is all correct, but has some logistical problems.
The main reason that simple pressure rockets tend to outperform
chemical rockets over short distance is the ignition delay. Over
such a short distance, this whole thing is going to be over in a
fairly small fraction of a second - most chemical engines will still
be sitting on the start line waiting for a fuel ignition.
As an extreme, you could always strap a
stick of dynamite to the back,