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I am curious as to whether anyone can confirm the explanation given
in the Jan 2018 "Figuring Physics" solution provided in the Physics
Teacher:
http://aapt.scitation.org/doi/10.1119/1.5021443
Basically, the question is whether cooling would occur if molecules
of every speed in a liquid had an equal chance of escape from the
surface. The answer given in the column is no, with a rationale that
the cooling occurs because the faster ones are the ones that are
leaving and the slower ones are left behind.
The reason I ask is because I used to use somewhat similar logic but
stopped,
I stopped for two reasons. First, the "slow molecules left behind"
implies that the remaining liquid becomes cooler than the vapor that
is produced. Second, I feel it obscures the fact that the process of
leaving (which is a sort of bond breaking) requires an extraction of
energy from the surroundings, regardless of whether the molecules
involved were initially going faster or slower.