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Highly-reflective roofing materials can actually receive an Energy Star rating if their solar reflectivity is higher than 65%. There is also a CRRC (Cool Roof Rating Council) certification for products meeting the Title 24
[2] I was up on the roof late one afternoon to paint some trim around the hatch and around the edge of the roof. The roof felt only a little above ambient temperature when the sun was on it. It absolutely was not hot. The amazing thing was when the sun went down. The roof got cold. Not ambient temperature... but cold. That white roof was radiating like crazy. I thought maybe I was imagining it, so I got a digital thermometer and placed it in contact with the roof and it was about 60 F when the ambient air temperature was about 72 F. This made me rethink my thoughts about blackbody radiators.