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Hi Tony-
You percieve a polished metal surcace as shiny because you are
looking at photons having fequency far below the frequency required to
generate photoelectrons. The surface appears shiny because the photons
are relected, and not absorbed.
Shininess is most easily understood as a classical effect. The
E-field of the light ray, incident on the metal, generates a current in
the conductive metal, the current, oscillating with the frequency of the
incident light ray, radiates EM energgy that you percieve as reflected
light.
Regards,
Jack