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Triboelectricity is a tricky topic. As John says, rubbing one metal
against another doesn't do it.
It will serve to remove the surface
films so that the metals are indeed in direct contact, and then
electron transfer can occur depending on the work functions.
Triboelecticity seems to occur most often when one of the materials
is a polymer. Sherwood and Chabay do a nice job of showing that the
energies involved are not sufficient to transfer electrons, but could
transfer charged polymer fragments.
So I don't think triboelectricity is the way to think about this.
Isn't the problem a matter of how to affectively couple to the
electrons...a hammer just doesn't do it.