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Re: Quasistatic conditions



Pentcho wrote:

The fact that a system is in equilibrium
all along does not guarantee that the change it undergoes is
quasistatic in the above sense. We can imagine a system
thermally isolated from HOTTER surroundings but still a thin
wire connects them so that the temperature of the system
increases very slowly. The system is in equilibrium (passes
through a succession of equilibrium states) but....what
type of process is this????
It is extremely important for us to answer this question.
Classically, the entropy is defined through dS=dQrev/T, but the
subscript "rev" may mean, according to textbooks, two things.
Either the system just passes through a succession of
equilibrium states, or the system passes through a succession
of equilibrium states but, in addition, exchanges heat with
the surroundings ONLY WHEN SYSTEM AND SURROUNDINGS ARE OF THE
SAME TEMPERATURE.

Interesting question.

But have you considered the possibility that there is a temperature
gradient along the wire so that each "mesoscopic portion" (in the
sense discussed by David) of the materials involved are in contact
with adjacent mesoscopic portions at only very slightly higher or
lower temperatures? Isn't this implied in the fact that the wire is
"thin"? Carl
--
Carl E. Mungan, Asst. Prof. of Physics 410-293-6680 (O) -3729 (F)
U.S. Naval Academy, Stop 9C, Annapolis, MD 21402-5040
mailto:mungan@usna.edu http://usna.edu/Users/physics/mungan/