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In the case of one ball being held stationary, the work done on the
balls (conventionally) is entirely due to the work done on the ball
that's moved. Say that the moved ball experiences a force F(x) at each
point along its path. To get the total work done on the balls
(conventionally), you need to integrate F.dx from the initial to the
final position for the moved ball. Say you get a value W for the work
done on the moved ball, in this situation. But conventionally, since no
work is done on the stationary ball, W is the total work done on the two
balls.
In the case of both balls being moved toward each other, say that each
ball experiences equal, but opposite, forces F(x) (not necessarily the
same F(x) as in the first case) at each point along its path. To get the
total work done on the balls (conventionally), you need to integrate
F.dx from the initial to the final position for each ball. Or you could
just double the work done on one ball, in this case. Calculating the
work done on the same ball as before, the distance it moves is half the
distance it moved in the first case, _but_ the force it experiences at
each point along its path is exactly _twice_ the force that it
experienced at that point, in the first case (look at the force as a
function of the distance between the balls).
So the work done on that ball is the same as the work done on it, in
the first case, since it moves half the distance, but experiences
twice the force. ... So the total work done on the two balls, in
this case, is _exactly _twice_ the work done in the first case.
Conventionally, this discrepancy can't be explained. It's only by
assuming that work is done on the stationary ball, that you can account
for the differences in work (energy).