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Velcro in its intended use does not store any significant amount of
potential energy. When two carts equipped with velcro collide, the "lost"
kinetic energy is indeed *dissipated*, not transformed into potential
energy of bent velcro barbs. If you find that the cart is launched with a
small velocity after being torn free, it is simply because you were
exerting a force on it in order to tear it free and *kept* exerting that
force for a short time *after* it broke free.