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Re: IONS/vacuum pedagogy



The range of the bound electrons outside the plane of the outer ion
cores is, as I recall a nm or so. The density falls off rapidly with
distance from that plane. However the charge separation causes a surface
dipole which contributes to the work function associated with the
surface. As a result, the value of the workfunction varies with the
degree of surface roughness and the contours created by the underlying
crystal. Thus the (100) surface has a different workfunction than the
(110). Both have larger workfunctions than the more rough (211). By the
way I thinking in terms of a bcc lattice as in Wolfram, ups pardon me,
Tungsten.

cheers

On Thu, 15 Oct 1998, Ludwik Kowalski wrote:

Sorry for the "vavuum" instead of "vacuum", in the subject
line. If the proposed explanation is acceptable (not conflicting
with known facts or theories) then one may be able to say that
electrons on the surface of a metallic sphere near a room
temperature are also a "space charge". A thin cloud called
layer instead of a thicker one at 2000 K.