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If I remember correctly from my astronomy days, the Luminance curve for our
sun peaks in the yellow portion of the spectrum. That doesn't mean it
necessaarily looks yellow (a psychological phenomenon).
However, if you
look at the spectrum for the sky, it is distinctly bluish (check out the
shadows in photographs of snow scenes).
The sun is decidedly more yellow
than this. If I stared at something as bright as the sun, it probably
wouldn't matter a whole lot what color it is!