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From: LUDWIK KOWALSKI <kowalskil@alpha.montclair.edu>
Yes, the word heat has two conflicting meanings in many introductoryphysics
textbooks. In thermodynamics it refers to that part of a thermal energychange
which is due to a difference of temperatures, dT, between the inside andin
outside of a system. It is a path-dependent quantity, usually expressed
joules. In elementary physics on the other hand, heat is the name givento
the quantity Q when the formula Q=c*m*dT is used to perform simplebody
calorimetric calculations. Students often say that the temperature of a
is determined by the amount of heat "it contains". Phrases such as "heatadded
to a body" or "heat removed from it" are commonly used by teachers whotake
it for granted that "heat" is a synonym for "thermal energy of moleculesand
atoms". The experiments of Joule are often interpreted by saying thatthermodynamics.
"energy in the form of heat" and "mechanical energy" are equivalent. In
thermodynamics, on the other hand, we emphasize that heat is not a state
function, such as energy or enthalpy.
Thus a common statement: "heat is a form of energy" is false in
This situation was created because the same name, "heat", was given tocalorimetry
different physical quantities expressed in joules. We use it in
and we use it in the first law, dE=Q+W. The recognition of this fact isan
important first step toward the elimination of many conceptual conflicts.We
must then decide what to do about this unfortunate situation. Should theterm
"heat" be eliminated from elementary calorimetry and replaced by"internal
energy"? I suspect that most phys-L-ers would favor this "modern"approach.
They would disagree with the following formulation, found in Sears andconverts
Zemansky. "The process of combustion releases the internal energy and
it into heat. In this form the energy can be utilized for ..."of
The other alternative is to retain the traditional meaning of heat (form
energy) and to invent a new name, for example, "thermal pseudo-energy",for
the path-dependent quantity Q in thermodynamics. This approach could behave
defended by observing that "heat" is a common word; introductory courses
traditionally been structured to quantify common words, such as force,work
and heat. Phrases, such as "energy in the form of heat", "heat releasedin a
reaction", "heat produced through friction" or "heat flows" are toodeeply
rooted to be abandoned. Renaming Q in thermodynamics would be lessconfusing
than renaming it in elementary physics. Wouldn't you agree with Jim thatthe
most effective way of confusing students and teachers is to redefinelearn
traditional words with which they are already familiar. Can students
thermodynamics before they learn calorimetry?that
By the way, I still think that a distinction between thermal energy and
internal energy can be very useful in many problems. Thermal energy is
part of internal energy which is associated with motions and interactionsof
molecules and atoms. The internal energy, on the other hand, is notlimited
to its thermal component; part of it may be associated with motions andbelts,
interactions of macroscopic components of a system, such as wheels,
springs and pistons. The internal energy does not change when frictionslows
down a brick sliding along a horizontal surface. But a conversion ofkinetic
energy into thermal energy does take place in the system.Kowalski
Ludwik